He Zhiyuan, Xue Xiaolian, Liu Yilan, Yu Na, Krogman Jeremy P
School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, China.
Dalton Trans. 2020 Sep 22;49(36):12586-12591. doi: 10.1039/d0dt00570c.
We report a method for the synthesis of amidinate stabilized silylene (NHSi) metal-halide complexes from M{N(SiMe3)2}2 (M = Mn, Fe, Co). The reported reactions can be used to make mono-silylene or bis-silylene complexes and the resulting products can be easily controlled by the reaction stoichiometry. Additionally, we apply this new synthetic protocol for the synthesis of a bis-iron complex derived from a bis-amidinate ligand having a terphenyl backbone.
我们报道了一种从M{N(SiMe₃)₂}₂（M = Mn、Fe、Co）合成脒基稳定的甲硅烯（NHSi）金属卤化物配合物的方法。所报道的反应可用于制备单甲硅烯或双甲硅烯配合物，并且所得产物可通过反应化学计量轻松控制。此外，我们将这种新的合成方案应用于合成一种源自具有三联苯骨架的双脒基配体的双铁配合物。
