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超支化聚合物在改性天然植物纤维及其在聚合物基复合材料中的应用研究进展。

Hyperbranched Polymers in Modifying Natural Plant Fibers and Their Applications in Polymer Matrix Composites-A Review.

机构信息

College of Material Science and Engineering and Hebei Key Laboratory of Material Near-Net Forming Technology , Hebei University of Science and Technology , Shijiazhuang 050018 , China.

出版信息

J Agric Food Chem. 2019 Aug 14;67(32):8715-8724. doi: 10.1021/acs.jafc.9b03436. Epub 2019 Aug 2.

Abstract

Natural plant fibers have been widely used in the agricultural and forest industries, and even in the automobile industry, especially for producing fiber reinforced polymer matrix composites. However, the low mechanical properties of composites remain the key problem in the applications. A hyperbranched polymer has lots of advantages such as low viscosity, high reactivity, and so on. Multireactive end groups of hyperbranched polymers are ideal for modifying natural plant fibers to achieve better interface bonding between a fiber and resin matrix. This manuscript reviews some research advances in hyperbranched-polymer-modified natural plant fibers and summarizes the applications of the modified fibers in polymer matrix composites with a particular focus on the chemical modification of fibers and interface bonding.

摘要

天然植物纤维已广泛应用于农业和林业行业,甚至在汽车工业中,特别是用于生产纤维增强聚合物基体复合材料。然而,复合材料的低机械性能仍然是其应用中的关键问题。超支化聚合物具有低粘度、高反应性等优点。超支化聚合物的多反应性端基是改性天然植物纤维的理想选择,可以实现纤维与树脂基体之间更好的界面结合。本文综述了超支化聚合物改性天然植物纤维的一些研究进展,并总结了改性纤维在聚合物基体复合材料中的应用,特别关注纤维的化学改性和界面结合。

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