含芘的 PN 衍生物的合成、结构和光物理性质。
PN-Containing Pyrene Derivatives: Synthesis, Structure, and Photophysical Properties.
机构信息
Department of Chemistry & Biochemistry and the Materials Science Institute , University of Oregon , Eugene , Oregon 97403-1253 , United States.
CAMCOR , University of Oregon , Eugene , Oregon 97403-1433 , United States.
出版信息
Org Lett. 2019 Aug 16;21(16):6427-6431. doi: 10.1021/acs.orglett.9b02332. Epub 2019 Jul 26.
A straightforward method for the preparation of non-K region fused phosphorus- and nitrogen-containing (PN)-heterocyclic pyrenes has been accomplished. Their structural, photophysical, and electrochemical properties have been fully investigated. The described compounds exhibit intriguing redox properties and show strong photoluminescence with a wide range of tunable emission colors, with λ ranging from blue at 459 nm to red at 622 nm in CHCl solution.
一种简单的方法用于制备非 K 区融合的磷和氮杂（PN）杂环并苯。其结构、光物理和电化学性质得到了充分的研究。所描述的化合物表现出有趣的氧化还原性质，并显示出强的光致发光，具有广泛可调的发射颜色，在 CHCl 溶液中 λ 从 459nm 的蓝色到 622nm 的红色。
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