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characterization of raw and alkali treated new natural cellulosic fibres extracted from the aerial roots of banyan tree.

Characterization of raw and alkali treated new natural cellulosic fibres extracted from the aerial roots of banyan tree.

机构信息

Department of Mechanical Engineering, Coimbatore Institute of Technology, Coimbatore, Tamilnadu, India.

Department of Mechanical Engineering, Kamaraj College of Engineering and Technology, Virudhunagar, Tamilnadu, India.

出版信息

Int J Biol Macromol. 2019 Oct 1;138:573-581. doi: 10.1016/j.ijbiomac.2019.07.136. Epub 2019 Jul 23.

Abstract

The objective of this investigation is to check the suitability novel cellulosic fibre extracted from the aerial roots of Banyan tree (ARBFs) as reinforcement in fibre reinforced plastics. The Fundamental properties of ARBFs such as density, tensile strength, chemical composition, crystallinity index, crystalline size, thermal stability, maximum degradation temperature and surface roughness were studied. The chemical analysis results revealed that after the alkalization cellulose content was improved while hemi-cellulose, lignin and wax content were demised. The enhancement in the crystallinity index (76.35% from 72.47%) and crystalline size (7.74 nm from 6.28 nm) of alkali treated ARBFs were evidenced by the X-ray diffraction analysis. Thermal analysis results confirmed that maximum degradation temperature (368 °C) and kinetic activation energy (75.45 kJ/mol) of alkali treated ARBFs had increased from 358 °C and 72.65 kJ/mol respectively. The results of scanning electron microscopic and atomic force microscopic analysis exhibited that impurities and wax on the outer surface of the ARBFs were removed after the alkali treatment. All the above finding concluded that ARBFs is the appropriate material to use as a reinforcement in fibre reinforced plastics.

摘要

本研究旨在考察从榕树气生根中提取的新型纤维素纤维作为纤维增强塑料增强材料的适用性。研究了气生根纤维的基本性能,如密度、拉伸强度、化学成分、结晶度指数、结晶尺寸、热稳定性、最大降解温度和表面粗糙度。化学分析结果表明,碱处理后纤维素含量增加,而半纤维素、木质素和蜡含量减少。X 射线衍射分析表明,碱处理气生根纤维的结晶度指数(从 72.47%提高到 76.35%)和结晶尺寸(从 6.28nm 增加到 7.74nm)有所提高。热分析结果证实,碱处理气生根纤维的最大降解温度(从 358°C 提高到 368°C)和动力学活化能(从 72.65kJ/mol 提高到 75.45kJ/mol)。扫描电子显微镜和原子力显微镜分析结果表明,碱处理后气生根纤维外表面的杂质和蜡被去除。综上所述,气生根纤维是一种适合用作纤维增强塑料增强材料的材料。

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