Balachandran Gurukarthik Babu, Narayanasamy P, Alexander Anandha Balaji, David Prince Winston, Mariappan Rajesh Kannan, Ramachandran Muthu Eshwaran, Indran Suyambulingam, Mavinkere Rangappa Sanjay, Siengchin Suchart
Department of Electrical and Electronics Engineering, Kamaraj College of Engineering and Technology, Virudhunagar, 626001, Tamil Nadu, India.
Department of Mechanical Engineering, Kamaraj College of Engineering and Technology, Virudhunagar, 626001, Tamil Nadu, India.
Heliyon. 2023 Oct 27;9(11):e21239. doi: 10.1016/j.heliyon.2023.e21239. eCollection 2023 Nov.
In this study, micro-cellulosic fibers were isolated from the bark of (MT) and characterized for the first time. The anatomical, physical, chemical, thermal, and mechanical properties of the bark fiber (MTBF) were investigated. The mean diameter and density values were determined to be 32.013 ± 1.43 μm and 1.4875 g/cm³, respectively. Zeta potential analysis and particle size measurements provided the evidence of enhanced micro-particle behavior on the fiber's surface. Various structural characterizations confirmed the presence of polysaccharide structures, monosaccharide compositions, glycosidic residues (sugar linkages), and cohesive reactions of TMSA (Trimethylsilyl alditol) derivatives, indicating the fiber's potential for strong surface absorption properties. X-ray diffraction analysis revealed a crystallinity index of 51 % and a crystallite size of 3.086 nm for MTBF. Fourier transform infrared analysis indicated the presence of cellulose, hemicellulose, and lignin constituents, along with their corresponding functional groups. The calculated values of Young's modulus and tensile strength were determined to be 75.7 GPa and 746.77 MPa, respectively. Thermogravimetric analysis demonstrated the thermal stability of the extracted MTBF up to 240 °C. Based on these findings, the MT microfibrils derived from the bark can be considered as potential substitutes for existing synthetic composites, offering reinforcement for novel bio composites.
在本研究中,首次从(MT)树皮中分离出微纤维素纤维,并对其进行了表征。研究了MT树皮纤维(MTBF)的解剖学、物理、化学、热学和力学性能。平均直径和密度值分别确定为32.013±1.43μm和1.4875g/cm³。zeta电位分析和粒度测量提供了纤维表面微粒行为增强的证据。各种结构表征证实了多糖结构、单糖组成、糖苷残基(糖键)以及TMSA(三甲基硅烷基糖醇)衍生物的内聚反应的存在,表明该纤维具有很强的表面吸收性能潜力。X射线衍射分析显示MTBF的结晶度指数为51%,微晶尺寸为3.086nm。傅里叶变换红外分析表明存在纤维素、半纤维素和木质素成分及其相应的官能团。计算得出的杨氏模量和拉伸强度值分别为75.7GPa和746.77MPa。热重分析表明提取的MTBF在高达240°C时具有热稳定性。基于这些发现,源自树皮的MT微纤丝可被视为现有合成复合材料的潜在替代品,为新型生物复合材料提供增强作用。