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基于银纳米线/碳纳米管复合材料的印花织物加热器。

Printed fabric heater based on Ag nanowire/carbon nanotube composites.

作者信息

Ahn Junseong, Gu Jimin, Hwang Boyeon, Kang Hyeokjung, Hwang Soonhyoung, Jeon Sohee, Jeong Junho, Park Inkyu

机构信息

Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea. Department of Nano Manufacturing Technology, Korea Institute of Machinery and Materials (KIMM), Daejeon 34103, Republic of Korea.

出版信息

Nanotechnology. 2019 Nov 8;30(45):455707. doi: 10.1088/1361-6528/ab35eb. Epub 2019 Jul 26.

DOI:10.1088/1361-6528/ab35eb
PMID:31349233
Abstract

The increasing demand for smart fabrics has inspired extensive research in the field of nanomaterial-based wearable heaters. However, existing stretchable heaters employ polymer substrates, and hence require additional substrate-fabric bonding that can result in high thermal contact resistance. Moreover, currently used stretchable fabric heaters suffer from high sheet resistance and require complex fabrication processes. In addition, conventional fabrication methods do not allow for patternability, thus hindering the fabrication of wearable heaters with diverse designs. Herein, we propose an improved spray coating method well suited for the preparation of patternable heaters on commercial fabrics, combining the structural stability of carbon nanotubes with the high electrical conductivity of Ag nanowires to fabricate a stretchable fabric heater with excellent mechanical (stretchability ≈ 50%) and electrical (sheet resistance ≈ 22 Ω sq) properties. The fabricated wearable heater reaches typical operating temperatures of 35 °C-55 °C at a low driving voltage of 3-5 V with a proper surface power density of 26.6-72.2 [Formula: see text] (heater area: [Formula: see text]) and maintains a stable heating temperature for more than 30 h. This heater shows a stable performance even when folded or rolled, thus being well suited for the practical wearable applications.

摘要

对智能织物日益增长的需求激发了在基于纳米材料的可穿戴加热器领域的广泛研究。然而,现有的可拉伸加热器采用聚合物基材,因此需要额外的基材与织物的粘结,这可能导致高的热接触电阻。此外,目前使用的可拉伸织物加热器具有高的面电阻,并且需要复杂的制造工艺。另外,传统的制造方法不允许图案化,从而阻碍了具有多样设计的可穿戴加热器的制造。在此,我们提出一种改进的喷涂方法,非常适合在商业织物上制备可图案化的加热器,将碳纳米管的结构稳定性与银纳米线的高导电性相结合,以制造具有优异机械性能(拉伸率≈50%)和电学性能(面电阻≈22Ω/sq)的可拉伸织物加热器。所制造的可穿戴加热器在3 - 5V的低驱动电压下,以26.6 - 72.2[公式:见原文](加热器面积:[公式:见原文])的适当表面功率密度达到35℃ - 55℃的典型工作温度,并保持稳定的加热温度超过30小时。即使折叠或卷起,该加热器也表现出稳定的性能,因此非常适合实际的可穿戴应用。

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