Needle ball-like nanostructured mixed Cu-Ni-Co oxides: Synthesis, characterization and application to the selective oxidation of sulfides to sulfoxides.

A mixed nano-metal oxides of Cu-Ni-Co has been synthesized. Several characterization techniques (EDS, XRD, TEM, and SEM) have been used to provide insight into the nature and structure of the catalyst. The size of this mixed metal oxide is 22 nm. The SEM images indicate that the sample with spherical particles, of which spherical assembly is comprised of elongated rod/needle-like subunits pointing radially outward, creates a needle ball-like structure. To efficiently catalyze the selective oxidation of sulfide towards sulfoxide, this heterogeneous catalyst uses an oxidizing agent (hydrogen peroxide- HO) and a solvent (acetonitrile) in mild conditions. The influence of reaction temperature and sulfide/oxidant molar ratio was evaluated with respect to sulfide conversion and chemoselectivity towards the sulfoxide product. Under optimized conditions, product yields in the range from 70 to 97% were obtained.