Goyal Navneet, Donahue James P, Do Camilla, Perry Timothy, Bongay-Williams Kyla, Foroozesh Maryam
Department of Chemistry, Xavier University of Louisiana, 1 Drexel Dr., New Orleans, Louisiana 70125, USA.
Department of Chemistry, Tulane University, 6400 Freret Street, New Orleans, Louisiana 70118-5698, USA.
IUCrdata. 2018 Sep;3(9). doi: 10.1107/S2414314618013068.
The title compound, CHO, crystallizes in two-dimensional sheets, in which the 2-(pentyloxy)dibenzo[,]furan molecules are arranged in a head-to-head and tail-to-tail fashion that enables hydrophobic interactions between fully extended 2-pentoxy chains and π-π stacking between dibenzofuran rings in adjacent rings. Nearest intermolecular π-π stacking contacts are 3.3731 (12) Å. The molecule is nearly planar with an r.m.s. deviation of 0.0803 Å from the mean plane defined by the nineteen non-hydrogen atoms.
标题化合物CHO以二维片层形式结晶，其中2-(戊氧基)二苯并[,]呋喃分子以头对头和尾对尾的方式排列，使得完全伸展的2-戊氧基链之间能够发生疏水相互作用，且相邻环中的二苯并呋喃环之间存在π-π堆积。最近的分子间π-π堆积接触距离为3.3731(12)Å。该分子近乎平面，相对于由19个非氢原子定义的平均平面的均方根偏差为0.0803Å。
