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取向二羧酸铜金属有机框架薄膜的气相沉积

Vapour-phase deposition of oriented copper dicarboxylate metal-organic framework thin films.

作者信息

Stassin Timothée, Rodríguez-Hermida Sabina, Schrode Benedikt, Cruz Alexander John, Carraro Francesco, Kravchenko Dmitry, Creemers Vincent, Stassen Ivo, Hauffman Tom, De Vos Dirk, Falcaro Paolo, Resel Roland, Ameloot Rob

机构信息

Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven, Celestijnenlaan 200F box 2454, 3000 Leuven, Belgium.

Institute of Solid State Physics, Graz University of Technology, Petersgasse 16, 8010 Graz, Austria.

出版信息

Chem Commun (Camb). 2019 Sep 4;55(68):10056-10059. doi: 10.1039/c9cc05161a. Epub 2019 Aug 1.

DOI:10.1039/c9cc05161a
PMID:31369024
Abstract

Copper dicarboxylate metal-organic framework films are deposited via chemical vapour deposition. Uniform films of CuBDC and CuCDC with an out-of-plane orientation and accessible porosity are obtained from the reaction of Cu and CuO with vaporised dicarboxylic acid linkers.

摘要

通过化学气相沉积法沉积二羧酸铜金属有机骨架薄膜。通过铜和氧化铜与汽化的二羧酸连接体反应，可获得具有面外取向和可及孔隙率的CuBDC和CuCDC均匀薄膜。

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