连续纯金属有机骨架膜和薄膜的制备方法：综述

Fabrication Methods of Continuous Pure Metal-Organic Framework Membranes and Films: A Review.

作者信息

Xing Qinglei, Xu Xiangyou, Li Haoqian, Cui Zheng, Chu Binrui, Xie Nihao, Wang Ziying, Bai Peng, Guo Xianghai, Lyu Jiafei

机构信息

Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China.

Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin University, Tianjin 300350, China.

出版信息

Molecules. 2024 Aug 16;29(16):3885. doi: 10.3390/molecules29163885.

DOI:10.3390/molecules29163885

PMID:39202964

原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11356928/

Abstract

Metal-organic frameworks (MOFs) have drawn intensive attention as a class of highly porous, crystalline materials with significant potential in various applications due to their tunable porosity, large internal surface areas, and high crystallinity. This paper comprehensively reviews the fabrication methods of pure MOF membranes and films, including in situ solvothermal synthesis, secondary growth, electrochemical deposition, counter diffusion growth, liquid phase epitaxy and solvent-free synthesis in the category of different MOF families with specific metal species, including Zn-based, Cu-based, Zr-based, Al-based, Ni-based, and Ti-based MOFs.

摘要

金属有机框架材料（MOFs）作为一类具有高度多孔性的晶体材料，因其可调节的孔隙率、大的内表面积和高结晶度，在各种应用中具有巨大潜力，已引起广泛关注。本文全面综述了纯MOF膜和薄膜的制备方法，包括原位溶剂热合成、二次生长、电化学沉积、反向扩散生长、液相外延以及在不同MOF家族类别中采用特定金属物种（包括锌基、铜基、锆基、铝基、镍基和钛基MOFs）的无溶剂合成。