Protic Imidazolium Polymer as Ion Conductor for Improved Oxygen Evolution Performance.

Improving the electrocatalytic performance of oxygen evolution reaction (OER) is essential for oxygen-involved electrochemical devices, including water splitting and rechargeable metal-air batteries. In this work, we report that the OER performance of commercial catalysts of IrO, CoO, and Pt-C can be improved by replacing the traditional Nafion ionomer with newly synthesized copolymers consisting of protonated imidazolium moieties such as ion conductors and binders in electrodes. Specifically, such an improvement in OER performance for all the tested catalysts is more significant in basic and neutral environments than that under acidic conditions. We anticipate that the results will provide new ideas for the conceptual design of electrodes for oxygen-involved electrochemical devices.