Jiangsu Key Laboratory of Advanced Functional Polymer Design and Application, Department of Polymer Science and Engineering, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China.
School of Engineering Technology, Eastern Michigan University, Ypsilanti, MI 48197, USA.
Chem Soc Rev. 2017 Feb 20;46(4):1124-1159. doi: 10.1039/c6cs00620e.
We review recent works on the synthesis and application of poly(ionic liquid)s (PILs). Novel chemical structures, different synthetic strategies and controllable morphologies are introduced as a supplement to PIL systems already reported. The primary properties determining applications, such as ionic conductivity, aqueous solubility, thermodynamic stability and electrochemical/chemical durability, are discussed. Furthermore, the near-term applications of PILs in multiple fields, such as their use in electrochemical energy materials, stimuli-responsive materials, carbon materials, and antimicrobial materials, in catalysis, in sensors, in absorption and in separation materials, as well as several special-interest applications, are described in detail. We also discuss the limitations of PIL applications, efforts to improve PIL physics, and likely future developments.
我们综述了近年来关于聚离子液体（PILs）的合成和应用的研究工作。介绍了新颖的化学结构、不同的合成策略和可控的形态，作为已经报道的 PIL 体系的补充。讨论了决定应用的主要性质，如离子电导率、水溶度、热力学稳定性和电化学/化学耐久性。此外，详细描述了 PIL 在多个领域的近期应用，如在电化学能源材料、刺激响应材料、碳材料和抗菌材料、在催化、在传感器、在吸收和分离材料以及几个特殊兴趣应用中的应用。我们还讨论了 PIL 应用的局限性、改进 PIL 物理性能的努力以及可能的未来发展。
