用于外消旋丙交酯等规选择性聚合的高性能苯并咪唑基氨基酚锌配合物。
High performance benzoimidazolyl-based aminophenolate zinc complexes for isoselective polymerization of rac-lactide.
作者信息
Gong Yanmei, Ma Haiyan
机构信息
Shanghai Key Laboratory of Functional Materials Chemistry and Laboratory of Organometallic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, P. R. China.
出版信息
Chem Commun (Camb). 2019 Aug 20;55(68):10112-10115. doi: 10.1039/c9cc04834k.
PMID:31384844
Abstract
Zinc complexes supported by achiral benzoimidazolyl-based aminophenolate ligands exhibit high catalytic activities and excellent isoselectivities toward the ring-opening polymerization of rac-lactide under mild conditions.
摘要
由非手性苯并咪唑基氨基酚盐配体支撑的锌配合物在温和条件下对消旋丙交酯的开环聚合表现出高催化活性和优异的等规选择性。
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