CuH 催化的 - 醌甲醚的不对称 1,6-共轭还原：三芳基甲烷和 1,1,2-三芳基乙烷的对映选择性合成。
CuH-Catalyzed Asymmetric 1,6-Conjugate Reduction of -Quinone Methides: Enantioselective Synthesis of Triarylmethanes and 1,1,2-Triarylethanes.
机构信息
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, College of Chemistry and Chemical Engineering , China West Normal University , No. 1, Shida Road , Nanchong 637002 , P.R. China.
State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering , Lanzhou University , 222 Tianshui Nanlu , Lanzhou 730000 , China.
出版信息
Org Lett. 2019 Aug 16;21(16):6397-6402. doi: 10.1021/acs.orglett.9b02308. Epub 2019 Aug 7.
The first copper hydride (CuH)-catalyzed asymmetric 1,6-conjugate reduction of -quinone methides is reported. This protocol provides a new method to access a variety of triarylmethanes and 1,1,2-triarylethanes in good yields with excellent enantioselectivities and broad functional group tolerance.
首次报道了铜氢化物（CuH）催化的不对称 1,6-共轭还原 - 醌甲叉。该方案提供了一种新的方法，可在良好的收率和优异的对映选择性以及广泛的官能团容忍度下获得各种三芳基甲烷和 1,1,2-三芳基乙烷。
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