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磁场增强了低浓度过氧化氢条件下管状二硫化物微马达的性能。

Magnetic Fields Enhanced the Performance of Tubular Dichalcogenide Micromotors at Low Hydrogen Peroxide Levels.

机构信息

Department of Analytical Chemistry, Physical Chemistry and Chemical Engineering, University of Alcalá, Madrid, Spain.

Chemical Research Institute "Andres M. Del Rio", University of Alcalá, Madrid, Spain.

出版信息

Chemistry. 2019 Oct 11;25(57):13157-13163. doi: 10.1002/chem.201902368. Epub 2019 Sep 18.

DOI:10.1002/chem.201902368
PMID:31390485
Abstract

Propulsion at the microscale has attracted significant research interest. In this work, a numerical simulation to explain the speed boost of up to 34 % experienced by transition metal dichalcogenides (TMD) based micromotors under the effect of applied magnetic fields is described. The simulations show that, when an external magnetic field is applied, the flow regime changes from turbulent to laminar. This causes an increase in the residence time of the fuel over the catalyst surface, which enhances the oxygen production. The more efficient generation and growth of the bubbles lead to an increase of the capillary force exerted by them. Interestingly, the effect is more pronounced as the level of fuel decrease. The validity of the model is also proven by comparing both theoretical and experimental results. Interestingly, the speed enhancement in magnetic mode depends on geometrical factors only, as a similar phenomenon was observed in a variety of microjets with a variable surface roughness. The understanding of such phenomena will open new avenues for understanding and controlling the motion behavior of high-towing-force catalytic micromotors.

摘要

微尺度推进引起了广泛的研究兴趣。在这项工作中,我们进行了数值模拟,以解释在外磁场作用下,基于过渡金属二硫化物(TMD)的微马达速度提高了 34%的原因。模拟结果表明,当施加外部磁场时,流型从湍流变为层流。这导致燃料在催化剂表面上的停留时间增加,从而促进了氧气的产生。气泡更高效地生成和生长导致毛细作用力增加。有趣的是,随着燃料水平的降低,这种效应更加明显。该模型的有效性还通过比较理论和实验结果得到了验证。有趣的是,磁场模式下的速度增强仅取决于几何因素,因为在具有不同表面粗糙度的各种微射流中也观察到了类似的现象。对这些现象的理解将为理解和控制高牵引力催化微马达的运动行为开辟新途径。

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