Naeem Sumayyah, Naeem Farah, Mujtaba Jawayria, Shukla Ashish Kumar, Mitra Shirsendu, Huang Gaoshan, Gulina Larisa, Rudakovskaya Polina, Cui Jizhai, Tolstoy Valeri, Gorin Dmitry, Mei Yongfeng, Solovev Alexander A, Dey Krishna Kanti
Department of Materials Science, Fudan University, Shanghai 200433, China.
State Key Laboratory for Modification of Chemical Fibers and Polymer Material Science and Engineering, Donghua University, Shanghai 201620, China.
Micromachines (Basel). 2021 Oct 15;12(10):1251. doi: 10.3390/mi12101251.
Gaseous oxygen plays a vital role in driving the metabolism of living organisms and has multiple agricultural, medical, and technological applications. Different methods have been discovered to produce oxygen, including plants, oxygen concentrators and catalytic reactions. However, many such approaches are relatively expensive, involve challenges, complexities in post-production processes or generate undesired reaction products. Catalytic oxygen generation using hydrogen peroxide is one of the simplest and cleanest methods to produce oxygen in the required quantities. Chemically powered micro/nanomotors, capable of self-propulsion in liquid media, offer convenient and economic platforms for on-the-fly generation of gaseous oxygen on demand. Micromotors have opened up opportunities for controlled oxygen generation and transport under complex conditions, critical medical diagnostics and therapy. Mobile oxygen micro-carriers help better understand the energy transduction efficiencies of micro/nanoscopic active matter by careful selection of catalytic materials, fuel compositions and concentrations, catalyst surface curvatures and catalytic particle size, which opens avenues for controllable oxygen release on the level of a single catalytic microreactor. This review discusses various micro/nanomotor systems capable of functioning as mobile oxygen generators while highlighting their features, efficiencies and application potentials in different fields.
气态氧在驱动生物体新陈代谢方面起着至关重要的作用,并且在农业、医学和技术领域有多种应用。人们已经发现了不同的制氧方法,包括植物制氧、氧气浓缩器和催化反应。然而,许多此类方法相对昂贵,存在挑战,生产后处理过程复杂,或者会产生不需要的反应产物。用过氧化氢催化产氧是按需生产所需量氧气的最简单、最清洁的方法之一。能够在液体介质中自行推进的化学驱动微纳马达,为按需即时产生气态氧提供了便捷且经济的平台。微纳马达为在复杂条件下控制氧气的产生和运输、关键的医学诊断和治疗开辟了机会。通过仔细选择催化材料、燃料成分和浓度、催化剂表面曲率以及催化颗粒大小,移动氧微载体有助于更好地理解微纳级活性物质的能量转换效率,这为在单个催化微反应器层面上可控地释放氧气开辟了途径。本综述讨论了各种能够作为移动氧发生器发挥作用的微纳马达系统,同时突出了它们的特点、效率以及在不同领域的应用潜力。