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- 氧化双[（5,10,15,20-四苯基卟啉合）铁（III）]一种多晶型物的晶体结构。

Crystal structure of a polymorph of -oxido-bis-[(5,10,15,20-tetra-phenyl-porphyrinato)iron(III)].

作者信息

Peters Morten K, Näther Christian, Herges Rainer

机构信息

Otto-Diels-Institut für Organische Chemie, Christian-Albrechts-Universität Kiel, Otto-Hahn-Platz 4, D-24098 Kiel, Germany.

Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth Str. 2, D-24118 Kiel, Germany.

出版信息

Acta Crystallogr E Crystallogr Commun. 2019 May 31;75(Pt 6):930-933. doi: 10.1107/S2056989019007576. eCollection 2019 Jun 1.

DOI:10.1107/S2056989019007576
PMID:31391997
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6658976/
Abstract

The title compound, [Fe(CHNO)O], was obtained as a by-product during the synthesis of Fe tetra-phenyl-porphyrin perchlorate. It crystallizes as a new polymorphic modification in addition to the ortho-rhom-bic form previously reported [Hoffman (1972 ▸). , 3620-3626; Swepston & Ibers (1985 ▸) C, 671-673; Kooijmann (2007 ▸). Private Communication (refcode 667666). CCDC, Cambridge, England]. In its crystal structure, the two crystallographically independent Fe cations are coordinated in a square-planar environment by the four N atoms of a tetra-phenyl-porphyrin ligand. The Fe-tetra-phenyl-porphyrine units are linked by a μ-oxido ligand into a dimer with an Fe-O-Fe angle close to linearity. The final coordination sphere for each Fe atom is square-pyramidal with the μ-oxido ligand in the apical position. The crystal under investigation consisted of two domains in a ratio of 0.691 (3): 0.309 (3).

摘要

标题化合物[Fe(CHNO)O]是在合成高氯酸铁四苯基卟啉过程中作为副产物得到的。除了之前报道的正交晶系形式[霍夫曼（1972▸），3620 - 3626；斯韦普斯顿和伊贝斯（1985▸）C，671 - 673；库伊曼（2007▸）。私人通信（参考代码667666）。英国剑桥晶体学数据中心]外，它以一种新的多晶型变体形式结晶。在其晶体结构中，两个晶体学独立的铁阳离子由四苯基卟啉配体的四个氮原子在平面正方形环境中配位。铁 - 四苯基卟啉单元通过一个μ - 氧化配体连接成一个二聚体，Fe - O - Fe角接近线性。每个铁原子的最终配位球是四方锥型，μ - 氧化配体处于顶端位置。所研究的晶体由两个畴组成，比例为0.691（3）: 0.309（3）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/fb890cfda88a/e-75-00930-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/3b3952cd8eed/e-75-00930-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/8f7da1a3f0cf/e-75-00930-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/94766a09045d/e-75-00930-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/fb890cfda88a/e-75-00930-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/3b3952cd8eed/e-75-00930-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/8f7da1a3f0cf/e-75-00930-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/94766a09045d/e-75-00930-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2a83/6658976/fb890cfda88a/e-75-00930-fig4.jpg

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本文引用的文献

1
Spin Switching with Triazolate-Strapped Ferrous Porphyrins.三唑连接的亚铁卟啉的自旋切换
Inorg Chem. 2019 Apr 15;58(8):5265-5272. doi: 10.1021/acs.inorgchem.9b00349. Epub 2019 Apr 2.
2
One-Pot Approach to Chlorins, Isobacteriochlorins, Bacteriochlorins, and Pyrrocorphins.一锅法合成叶绿素、类菌绿素、细菌叶绿素和吡咯并卟啉。
Org Lett. 2018 Dec 21;20(24):7879-7883. doi: 10.1021/acs.orglett.8b03433. Epub 2018 Dec 11.
3
Light-controlled switching of the spin state of iron(III).光控铁(III)自旋态的转换。
Nat Commun. 2018 Nov 12;9(1):4750. doi: 10.1038/s41467-018-07023-1.
4
Crystal structure of 2-[2-(pyridin-3-yl)diazen-1-yl]aniline.2-[2-(吡啶-3-基)重氮-1-基]苯胺的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Jun 26;74(Pt 7):1013-1016. doi: 10.1107/S2056989018008605. eCollection 2018 Jul 1.
5
Insertion of Ni(I) into Porphyrins at Room Temperature: Preparation of Ni(II)porphyrins, and Ni(II)chlorins and Observation of Hydroporphyrin Intermediates.室温下卟啉环中镍（Ⅱ）的嵌入：镍（Ⅱ）卟啉、镍（Ⅱ）氯卟啉的制备及水卟啉中间体的观察。
Inorg Chem. 2018 Mar 19;57(6):3177-3182. doi: 10.1021/acs.inorgchem.7b03164. Epub 2018 Mar 2.
6
The Cambridge Structural Database.剑桥结构数据库。
Acta Crystallogr B Struct Sci Cryst Eng Mater. 2016 Apr;72(Pt 2):171-9. doi: 10.1107/S2052520616003954. Epub 2016 Apr 1.
7
Photoswitchable Magnetic Resonance Imaging Contrast by Improved Light-Driven Coordination-Induced Spin State Switch.通过改进的光驱动配位诱导自旋态转变实现光开关磁共振成像对比剂
J Am Chem Soc. 2015 Jun 24;137(24):7552-5. doi: 10.1021/jacs.5b00929. Epub 2015 May 5.
8
Magnetic bistability of molecules in homogeneous solution at room temperature.室温下均相溶液中分子的磁双稳性。
Science. 2011 Jan 28;331(6016):445-8. doi: 10.1126/science.1201180.
9
The role of porphyrin chemistry in tumor imaging and photodynamic therapy.卟啉化学在肿瘤成像和光动力治疗中的作用。
Chem Soc Rev. 2011 Jan;40(1):340-62. doi: 10.1039/b915149b. Epub 2010 Aug 9.
10
Nickel homeostasis and nickel regulation: an overview.镍稳态与镍调节：概述
Chem Rev. 2009 Oct;109(10):4617-43. doi: 10.1021/cr900010n.