二（四甲基铵）四氯合铜（II）单斜相（IV相）的晶体结构
Crystal structure of the monoclinic phase (phase IV) of bis-(tetra-methyl-ammonium) tetra-chlorido-cuprate(II).
作者信息
Seck Gorgui Awa, Diop Libasse, Oliver Allen G
机构信息
Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Senegal.
Department of Chemistry and Biochemistry, University of Notre Dame, IN 46557-5670, USA.
出版信息
Acta Crystallogr E Crystallogr Commun. 2017 Feb 14;73(Pt 3):358-360. doi: 10.1107/S2056989017002146. eCollection 2017 Mar 1.
The crystal structure of the low-temperature monoclinic phase of the title compound, [(CH)N][CuCl], was determined at 120 K. The structure of the room-temperature phase has been determined in the ortho-rhom-bic space group [Morosin & Lingafelter (1961 ▸). 50-51; Clay (1975 ▸). B 289-290]. The asymmetric unit consists of one discrete tetra-chlorido-cuprate anion with a distorted tetra-hedral geometry and two tetra-methyl-ammonium cations. In the crystal, the cations and the anions are linked weak C-H⋯Cl hydrogen bonds.
在120 K下测定了标题化合物[(CH)N][CuCl]低温单斜相的晶体结构。室温相的结构已在正交空间群中确定[莫罗辛和林加费尔特（1961 ▸）。50 - 51；克莱（1975 ▸）。B 289 - 290]。不对称单元由一个具有扭曲四面体几何形状的离散四氯合铜酸盐阴离子和两个四甲基铵阳离子组成。在晶体中，阳离子和阴离子通过弱的C-H⋯Cl氢键相连。
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