Romero Francisco J, Rivadeneyra Almudena, Ortiz-Gomez Inmaculada, Salinas Alfonso, Godoy Andrés, Morales Diego P, Rodriguez Noel
Pervasive Electronics Advanced Research Laboratory, University of Granada, 18071 Granada, Spain.
Department of Electronics and Computer Technology, University of Granada, 18071 Granada, Spain.
Nanomaterials (Basel). 2019 Aug 21;9(9):1184. doi: 10.3390/nano9091184.
In this paper, we present a simple and inexpensive method for the fabrication of high-performance graphene-based heaters on different large-scale substrates through the laser photothermal reduction of graphene oxide (laser-reduced graphene-oxide, LrGO). This method allows an efficient and localized high level of reduction and therefore a good electrical conductivity of the treated films. The performance of the heaters is studied in terms of steady-state temperature, power consumption, and time response for different substrates and sizes. The results show that the LrGO heaters can achieve stable steady-state temperatures higher than 200 °C when a voltage of 15 V is applied, featuring a time constant of around 4 s and a heat transfer coefficient of ~200 °C cm/W. These characteristics are compared with other technologies in this field, demonstrating that the fabrication approach described in this work is competitive and promising to fabricate large-scale flexible heaters with a very fast response and high steady-state temperatures in a cost-effective way. This technology can be easily combined with other fabrication methods, such as screen printing or spray-deposition, for the manufacturing of complete sensing systems where the temperature control is required to adjust functionalities or to tune sensitivity or selectivity.
在本文中,我们展示了一种简单且低成本的方法,通过氧化石墨烯的激光光热还原(激光还原氧化石墨烯,LrGO)在不同的大规模基板上制备高性能的基于石墨烯的加热器。该方法允许进行高效且局部的高水平还原,从而使处理后的薄膜具有良好的导电性。针对不同的基板和尺寸,从稳态温度、功耗和时间响应方面研究了加热器的性能。结果表明,当施加15 V电压时,LrGO加热器能够实现高于200°C的稳定稳态温度,时间常数约为4 s,传热系数约为200°C·cm/W。将这些特性与该领域的其他技术进行了比较,表明本文所述的制造方法具有竞争力,有望以经济高效的方式制造具有非常快速响应和高稳态温度的大规模柔性加热器。该技术可以很容易地与其他制造方法(如丝网印刷或喷涂沉积)相结合,用于制造需要温度控制来调节功能或调整灵敏度或选择性的完整传感系统。