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溶剂热法合成锰锡氧化物微球及其作为催化剂和添加剂的应用研究。

Synthesis of manganese-tin oxide microparticles by the solvothermal method and study of application as a catalyst and additive.

机构信息

Laboratory of Super Light Materials and Nanotechnology, Department of Chemistry, University of Agriculture, Faisalabad, Pakistan.

Department of Medicine, Cholistan University of Veterinary and Animal Sciences, Bahawalpur, Pakistan.

出版信息

Environ Technol. 2021 Mar;42(8):1187-1195. doi: 10.1080/09593330.2019.1660414. Epub 2019 Aug 29.

DOI:10.1080/09593330.2019.1660414
PMID:31448700
Abstract

Manganese-tin bimetallic oxide (MnSnO) is synthesized by the solvothermal approach using manganese acetate and stannic chloride as precursors and urea as a precipitating agent in an aqueous medium. The crystallinity, purity and lattice parameters of the product are analysed by the X-ray diffraction analysis. The morphology of the product is analysed with the help of a scanning electron microscopy. The synthesized product is used as a fuel additive and catalyst. Synthesized MnSnO is used as a catalyst for the degradation of an organic dye Congo red in the aqueous medium. Catalytic degradation is monitored at different concentrations of the catalyst and hydrogen peroxide. Moreover, the role of MnSnO as an additive in diesel fuel, is studied. The efficiency of the modified fuel is analysed by studying the different parameters such as flash point, fire point, cloud point, pour point, calorific values and specific gravity. The values of these parameters change significantly by changing the dosage of the additive.

摘要

锰锡金属氧化物(MnSnO)是通过溶剂热法合成的,以醋酸锰和四氯化锡为前体,尿素为沉淀剂,在水介质中进行。通过 X 射线衍射分析对产物的结晶度、纯度和晶格参数进行分析。借助扫描电子显微镜分析产物的形态。合成的产物用作燃料添加剂和催化剂。合成的 MnSnO 用作水介质中有机染料刚果红的降解催化剂。在不同浓度的催化剂和过氧化氢的作用下,监测催化降解过程。此外,还研究了 MnSnO 作为柴油燃料添加剂的作用。通过研究闪点、燃点、浊点、倾点、热值和比重等不同参数来分析改性燃料的效率。通过改变添加剂的用量,这些参数的值会发生显著变化。

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