Department of Chemistry, Renmin University of China, Beijing, 100872, China.
Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China.
Chem Asian J. 2019 Oct 1;14(19):3350-3356. doi: 10.1002/asia.201900990. Epub 2019 Sep 5.
Eutectic molecular liquids (EMLs) based on hydrogen-bonding interaction and π-π stacking were prepared. We found that the thermodynamic properties like initial decomposition temperature and glass transition temperature of EMLs are mainly dominated by the hydrogen bond donor, which is beneficial for designing and preparing new EMLs. These new liquid systems could be applied in the field of environmental and material science.
基于氢键相互作用和π-π 堆积制备了低共熔分子液体(EML)。我们发现 EML 的热力学性质,如初始分解温度和玻璃化转变温度,主要由氢键供体决定,这有利于设计和制备新型 EML。这些新型液体体系有望在环境和材料科学领域得到应用。