Suttle M D, Twegar K, Nava J, Spiess R, Spratt J, Campanale F, Folco L
Dipartimento di Scienze della Terra, Università di Pisa, 56126, Pisa, Italy.
Department of Chemistry, Istanbul Technological University, 34467, Istanbul, Turkey.
Sci Rep. 2019 Aug 27;9(1):12426. doi: 10.1038/s41598-019-48937-0.
We report the discovery of a unique micrometeorite, containing an exotic Al-Cu-Fe alloy composed of two intermixed phases: khatyrkite (CuAl) and stolperite (CuAl) and both containing minor Fe (<1.4 wt%). These phases are dendritic and rapidly co-crystallized at the binary system's peritectic (550 °C). The host micrometeorite is an otherwise typical S-type micro-porphyritic cosmic spherule containing relict olivine (Fo76-90, CrO: 0.01-0.56 wt%, MnO: 0.03-0.32 wt% and CaO: 0.09-0.22 wt%) and a cumulate layered texture. These properties suggest the micrometeorite is derived from a carbonaceous chondrite (best matched to a CO chondrite) and entered the atmosphere a high speed (16 kms), implying an origin from a highly eccentric orbit. This particle represents the second independent discovery of naturally occurring intermetallic Al-Cu-Fe alloys and is thus similar to the previously reported Khatyrka meteorite - a CV chondrite containing near-identical alloys and the only known natural quasicrystals. We did not observe quasicrystalline phases in this micrometeorite, likely due to the low amounts of Fe in the alloy, insufficient to stabilize quasicrystals. Our discovery confirms the existence of Al-Cu-Fe intermetallic alloys on chondritic parent bodies. These unusual phases require a currently unexplained formation process, we tentatively suggest this could represent the delivery of exotic interstellar material to the inner solar system via impact.
我们报告发现了一种独特的微陨石,它含有一种由两种混合相组成的奇异铝铜铁合金:哈泰尔矿(CuAl)和斯托尔佩石(CuAl),两者均含有少量铁(<1.4 wt%)。这些相呈树枝状,在二元系统的包晶点(约550°C)迅速共结晶。主体微陨石是一种典型的S型微斑状宇宙球粒,含有残余橄榄石(Fo76 - 90,CrO:0.01 - 0.56 wt%,MnO:0.03 - 0.32 wt%,CaO:0.09 - 0.22 wt%)和堆积层状结构。这些特性表明该微陨石源自碳质球粒陨石(与CO球粒陨石最匹配),并以高速(约16公里/秒)进入大气层,这意味着其起源于高度偏心的轨道。这个颗粒是天然存在的金属间铝铜铁合金的第二个独立发现,因此与之前报道的哈泰尔卡陨石相似——一种含有近乎相同合金和唯一已知天然准晶体的CV球粒陨石。我们在这种微陨石中未观察到准晶相,可能是由于合金中铁含量低,不足以稳定准晶体。我们的发现证实了球粒陨石母体上存在铝铜铁金属间合金。这些不寻常的相需要一个目前无法解释清楚的形成过程,我们初步认为这可能代表着通过撞击将奇异的星际物质输送到内太阳系。