拓展新型氰化反应的范围：设计与合成具有极低最低未占分子轨道能级及改善溶解性的蒽衍生物

Extending the Scope of a New Cyanation: Design and Synthesis of an Anthracene Derivative with an Exceptionally Low LUMO Level and Improved Solubility.

作者信息

Glöcklhofer Florian, Morawietz Andreas J, Stöger Berthold, Unterlass Miriam M, Fröhlich Johannes

机构信息

Institute of Applied Synthetic Chemistry, TU Wien, Getreidemarkt 9/163, 1060 Vienna, Austria.

Institute of Chemical Technologies and Analytics, TU Wien, Getreidemarkt 9/164, 1060 Vienna, Austria.

出版信息

ACS Omega. 2017 Apr 24;2(4):1594-1600. doi: 10.1021/acsomega.7b00245. eCollection 2017 Apr 30.

The preparation of cyanated acenes from quinones has been improved for the conversion of electron-poor starting materials. The new procedure was used to prepare rationally designed 2,7-dinitro-9,10-dicyanoanthracene. Crystallographic, morphological, and electrochemical investigations have revealed most promising properties for applications in organic electronics.