Department of Chemistry and Centre for Advanced Solar Materials, University of Calgary, Calgary, AB, Canada.
Phys Chem Chem Phys. 2013 Jun 21;15(23):9007-24. doi: 10.1039/c3cp51379c. Epub 2013 May 14.
Conjugated materials have attracted much attention toward applications in organic electronics in recent years. These organic species offer many advantages as potential replacement for conventional materials (i.e., silicon and metals) in terms of cheap fabrication and environmentally benign devices. While p-type (electron-donating or hole-conducting) materials have been extensively reviewed and researched, their counterpart n-type (electron-accepting or electron-conducting) materials have seen much less popularity despite the greater need for improvement. In addition to developing efficient charge transport materials, it is equally important to provide a means of charge storage, where energy can be used on an on-demand basis. This perspective is focused on discussing a selection of representative n-type materials and the efforts toward improving their charge-transport efficiencies. Additionally, this perspective will also highlight recent organic materials for battery components and the efforts that have been made to improve their environmental appeal.
近年来,共轭材料在有机电子领域的应用引起了广泛关注。与传统材料(如硅和金属)相比,这些有机材料在廉价制造和环境友好型器件方面具有许多优势,作为潜在替代品。虽然 p 型(供电子或空穴传导)材料已经得到了广泛的综述和研究,但它们的 n 型(受电子或电子传导)对应材料尽管需求更大,但却鲜有人关注,尽管 n 型材料的需求更大。除了开发高效的电荷输运材料之外,提供一种电荷存储的方法同样重要,以便在需要时使用能量。本观点集中讨论了一系列具有代表性的 n 型材料以及提高其电荷输运效率的努力。此外,本观点还将重点介绍用于电池组件的最新有机材料以及为提高其环境吸引力所做的努力。