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用于多相应用的源自胶原蛋白生物废料的双功能杂化复合材料。

Bifunctional Hybrid Composites from Collagen Biowastes for Heterogeneous Applications.

作者信息

Mekonnen Berhanu Telay, Ragothaman Murali, Palanisamy Thanikaivelan

机构信息

Advanced Materials Laboratory, Central Leather Research Institute (Council of Scientific and Industrial Research), Adyar, Chennai 600020, India.

Academy of Scientific and Innovative Research, Training & Development Complex, CSIR Campus, CSIR Road, Taramani, Chennai 600113, India.

出版信息

ACS Omega. 2017 Aug 31;2(8):5260-5270. doi: 10.1021/acsomega.7b01011.

Abstract

We report the synthesis of an electrically conductive and magnetically active hybrid biocomposite comprising collagen and polyaniline (PAni) as the matrix and iron oxide nanoparticles (IONPs) as the filler through an in situ polymerization technique. Here, the matrix biopolymer, collagen, was extracted from trimmed wastes of animal hides generated from the leather industry. The as-synthesized C/PAni/IONP hybrid biocomposite powder possesses excellent electrical conductivity, thermal stability, and saturation magnetization, thereby providing scope for a wide range of applications. We show that the bifunctional composite has an ability to conduct electrons using a light emitting diode and battery setup, degrade dye under sunlight owing to its inherent photocatalytic activity, and absorb oil from oil-water mixtures with easier collection under magnetic tracking. We also demonstrate that the composite has remarkable electromagnetic interference shielding in the X-band frequency range. The results suggest that biowastes can be converted into useful high-value hybrid materials for applications in catalysis, biological, electronic, and environmental fields, thereby presenting a scalable and sustainable approach.

摘要

我们报道了一种导电且具有磁活性的杂化生物复合材料的合成,该复合材料以胶原蛋白和聚苯胺(PAni)为基质,以氧化铁纳米颗粒(IONPs)为填料,通过原位聚合技术制备而成。在此,基质生物聚合物胶原蛋白是从皮革工业产生的动物皮革修剪废料中提取的。合成的C/PAni/IONP杂化生物复合粉末具有优异的导电性、热稳定性和饱和磁化强度,从而为广泛的应用提供了空间。我们表明,这种双功能复合材料能够使用发光二极管和电池装置传导电子,由于其固有的光催化活性,在阳光下可降解染料,并且能从油水混合物中吸收油,在磁跟踪下更易于收集。我们还证明,该复合材料在X波段频率范围内具有显著的电磁干扰屏蔽性能。结果表明,生物废料可以转化为有用的高价值杂化材料,用于催化、生物、电子和环境领域,从而提供了一种可扩展且可持续的方法。

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