Facile Synthesis of Thiol-Functionalized Magnetic Activated Carbon and Application for the Removal of Mercury(II) from Aqueous Solution.

To improve the adsorption capacity, reduce the disposal cost, and enhance the separation efficiency of common activated carbon as an adsorbent in wastewater treatment, a novel thiol-modified magnetic activated carbon adsorbent of NiFeO-PAC-SH was successfully synthesized with a facile and safe hydrothermal method without any toxic and harmful reaction media. The as-prepared NiFeO-PAC-SH can effectively remove mercury(II) ions from aqueous solution. The maximal adsorption capacities from the experiment and Langmuir fitting achieve 298.8 and 366.3 mg/g at pH 7, respectively, exceeding most of adsorptive materials. The as-prepared NiFeO-PAC-SH has an outstanding regeneration performance, remarkable hydrothermal stability, and efficient separation efficiency. The data of kinetics, isotherms, and thermodynamics show that the adsorption of mercury(II) ions is spontaneous and exothermic. Ion exchange and electrostatic attraction are the main adsorption factors. The experimental results exhibit that the NiFeO-PAC-SH can be a prominent substitute for conventional activated carbon as an adsorbent.