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硅铝磷酸盐(SAPO)模板活性炭

Silicoaluminophosphate (SAPO)-Templated Activated Carbons.

作者信息

Li Yunxiang, Wang Xia, Thersleff Thomas, Svensson Gunnar, Hedin Niklas

机构信息

Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden.

出版信息

ACS Omega. 2019 Jun 7;4(6):9889-9895. doi: 10.1021/acsomega.9b00135. eCollection 2019 Jun 30.

Abstract

Microporous activated carbon was prepared by depositing and pyrolyzing propylene within the microporous voids of SAPO-37 and subsequently removing the template by a treatment with HCl and NaOH. The carbon had a high surface area and large micropore and ultramicropore volumes. The yield, crystallinity, morphology, and adsorption properties compared well with those of a structurally related zeolite-Y-templated carbon. No HF was needed to remove the SAPO-37 template in contrast to the zeolite Y template, which could be of industrial importance.

摘要

通过在SAPO - 37的微孔孔隙内沉积和热解丙烯,随后用HCl和NaOH处理以去除模板,制备了微孔活性炭。该碳具有高表面积以及大的微孔和超微孔体积。其产率、结晶度、形态和吸附性能与结构相关的Y型沸石模板碳相比具有优势。与Y型沸石模板不同,去除SAPO - 37模板不需要HF,这可能具有工业重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/e119896a7716/ao-2019-00135k_0001.jpg

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