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硅铝磷酸盐(SAPO)模板活性炭

Silicoaluminophosphate (SAPO)-Templated Activated Carbons.

作者信息

Li Yunxiang, Wang Xia, Thersleff Thomas, Svensson Gunnar, Hedin Niklas

机构信息

Department of Materials and Environmental Chemistry, Stockholm University, SE-10691 Stockholm, Sweden.

出版信息

ACS Omega. 2019 Jun 7;4(6):9889-9895. doi: 10.1021/acsomega.9b00135. eCollection 2019 Jun 30.

DOI:10.1021/acsomega.9b00135
PMID:31460079
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6648489/
Abstract

Microporous activated carbon was prepared by depositing and pyrolyzing propylene within the microporous voids of SAPO-37 and subsequently removing the template by a treatment with HCl and NaOH. The carbon had a high surface area and large micropore and ultramicropore volumes. The yield, crystallinity, morphology, and adsorption properties compared well with those of a structurally related zeolite-Y-templated carbon. No HF was needed to remove the SAPO-37 template in contrast to the zeolite Y template, which could be of industrial importance.

摘要

通过在SAPO - 37的微孔孔隙内沉积和热解丙烯,随后用HCl和NaOH处理以去除模板,制备了微孔活性炭。该碳具有高表面积以及大的微孔和超微孔体积。其产率、结晶度、形态和吸附性能与结构相关的Y型沸石模板碳相比具有优势。与Y型沸石模板不同,去除SAPO - 37模板不需要HF,这可能具有工业重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/0b1150845311/ao-2019-00135k_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/e119896a7716/ao-2019-00135k_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/67e2b22319c8/ao-2019-00135k_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/ceab9371c1ac/ao-2019-00135k_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/fa1451a03132/ao-2019-00135k_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/ad964e7ff6fa/ao-2019-00135k_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/5c2da003079f/ao-2019-00135k_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/0b1150845311/ao-2019-00135k_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/e119896a7716/ao-2019-00135k_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/67e2b22319c8/ao-2019-00135k_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/ceab9371c1ac/ao-2019-00135k_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/fa1451a03132/ao-2019-00135k_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/ad964e7ff6fa/ao-2019-00135k_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/5c2da003079f/ao-2019-00135k_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/96c1/6648489/0b1150845311/ao-2019-00135k_0007.jpg

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本文引用的文献

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Carbogenic nanodots derived from organo-templated zeolites with modulated full-color luminescence.源自具有调制全色发光的有机模板沸石的碳质纳米点。
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具有 EMT 结构类型的沸石模板炭的结构和吸附性能。
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Three-dimensionally arrayed and mutually connected 1.2-nm nanopores for high-performance electric double layer capacitor.用于高性能双电层电容器的三维排列且相互连通的 1.2nm 纳米孔
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How realistic is the pore size distribution calculated from adsorption isotherms if activated carbon is composed of fullerene-like fragments?如果活性炭由类富勒烯片段组成,那么根据吸附等温线计算出的孔径分布有多现实?
Phys Chem Chem Phys. 2007 Nov 28;9(44):5919-27. doi: 10.1039/b710552e. Epub 2007 Oct 2.
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Understanding the dissolution of zeolites.了解沸石的溶解过程。
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Preparation and hydrogen storage properties of zeolite-templated carbon materials nanocast via chemical vapor deposition: effect of the zeolite template and nitrogen doping.通过化学气相沉积法纳米铸造制备的沸石模板碳材料的储氢性能:沸石模板和氮掺杂的影响
J Phys Chem B. 2006 Sep 21;110(37):18424-31. doi: 10.1021/jp0639849.
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First zeolite carbon replica with a well resolved X-ray diffraction pattern.
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