School of Materials Science and Engineering, Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, P. R. China.
Dalton Trans. 2019 Sep 17;48(36):13541-13545. doi: 10.1039/c9dt02694k.
Simultaneously involving abundant [NH2(CH3)2]+ cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous CoII-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N2. GCMC theoretical simulations provide good verification of the experimental results.
同时含有丰富的[NH2(CH3)2]+阳离子和未配位的羧基氧原子作为双活性位，两种微孔 CoII-MOFs（LCU-105 和 LCU-106，LCU = 聊城大学）都表现出对 CO2/CH4 和 CO2/N2 的高选择性吸附。GCMC 理论模拟为实验结果提供了很好的验证。
