Li Yun-Wu, Yan Hui, Hu Tong-Liang, Ma Hui-Yan, Li Da-Cheng, Wang Su-Na, Yao Qing-Xia, Dou Jian-Min, Xu Jian, Bu Xian-He
School of Chemistry and Chemical Engineering, School of Materials Science and Engineering, School of Pharmacy, and Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, P. R. China.
School of Materials Science and Engineering, College of Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China.
Chem Commun (Camb). 2017 Feb 16;53(15):2394-2397. doi: 10.1039/c6cc09923h.
Two Fe-based porous MOFs have been constructed from dimeric Fe-clusters and rod-shaped heterobimetallic {FeNa} chains as SBUs, respectively. Both of them exhibit highly selective CO adsorption over CH and N, owing to their abundant multiple active sites.
两种铁基多孔金属有机框架分别由二聚体铁簇和棒状异双金属{FeNa}链作为次级结构单元构建而成。由于它们具有丰富的多个活性位点，二者对一氧化碳的吸附表现出对甲烷和氮气的高度选择性。
