Department of Chemistry, New York University, New York, NY 10003.
Department of Chemistry, New York University, New York, NY 10003
Proc Natl Acad Sci U S A. 2019 Sep 17;116(38):18783-18789. doi: 10.1073/pnas.1906976116. Epub 2019 Aug 30.
Safety risks associated with modern high energy-dense rechargeable cells highlight the need for advanced battery screening technologies. A common rechargeable cell exposed to a uniform magnetic field creates a characteristic field perturbation due to the inherent magnetism of electrochemical materials. The perturbation pattern depends on the design, state of charge, accumulated mechanical defects, and manufacturing flaws of the device. The quantification of the induced magnetic field with MRI provides a basis for noninvasive battery diagnostics. MRI distortions and rapid signal decay are the main challenges associated with strongly magnetic components present in most commercial cells. These can be avoided by using Single-Point Ramped Imaging with enhancement (SPRITE). The method is immune to image artifacts arising from strong background gradients and eddy currents. Due to its superior image quality, SPRITE is highly sensitive to defects and the state of charge distribution in commercial Li-ion cells.
与现代高能量密度可充电电池相关的安全风险突出了先进电池筛选技术的必要性。常见的可充电电池暴露在均匀磁场中,由于电化学材料的固有磁性,会产生特征磁场干扰。这种干扰模式取决于设备的设计、充电状态、累积的机械缺陷和制造缺陷。MRI 对感应磁场的定量分析为非侵入性电池诊断提供了基础。MRI 失真和信号快速衰减是大多数商用电池中存在的强磁场组件所带来的主要挑战。使用增强型单点 ramped 成像(Single-Point Ramped Imaging with enhancement,SPRITE)可以避免这些问题。该方法不受强背景梯度和涡流产生的图像伪影的影响。由于其卓越的图像质量,SPRITE 对商用锂离子电池的缺陷和充电状态分布非常敏感。