School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China.
Chem Commun (Camb). 2019 Sep 17;55(75):11247-11250. doi: 10.1039/c9cc06004a.
Pt nanoparticles directly anchored over a Te nanorod support fabricated by a microwave reduction approach instead of the 'sacrificial template' process were promising alternative catalysts for methanol oxidation in both acidic and alkaline electrolytes. The high catalytic performance could be attributed to the oxophilic properties of Te-induced electronic effect and ligand effect.
Pt 纳米颗粒直接锚定在通过微波还原方法制备的 Te 纳米棒载体上,而不是通过“牺牲模板”工艺,是酸性和碱性电解质中甲醇氧化的有前途的替代催化剂。这种高催化性能可归因于 Te 诱导的电子效应和配体效应的亲氧性质。