Rogge Torben, Ackermann Lutz
Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstraße 2, 37077, Göttingen, Germany.
Angew Chem Int Ed Engl. 2019 Oct 28;58(44):15640-15645. doi: 10.1002/anie.201909457. Epub 2019 Sep 20.
Experimental and computational studies provide detailed insight into the selectivity- and reactivity-controlling factors in bifurcated ruthenium-catalyzed direct C-H arylations and dehydrogenative C-H/C-H functionalizations. Thorough investigations revealed the importance of arene-ligand-free complexes for the formation of biscyclometalated intermediates within a ruthenium(II/IV/II) mechanistic manifold.
实验和计算研究为分叉钌催化的直接C-H芳基化和脱氢C-H/C-H官能团化反应中选择性和反应性的控制因素提供了详细的见解。深入研究揭示了无芳烃配体的配合物对于在钌（II/IV/II）机理体系中形成双环金属化中间体的重要性。
