State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanjing, 210096, China.
Small. 2020 Mar;16(9):e1903849. doi: 10.1002/smll.201903849. Epub 2019 Sep 4.
Understanding the relationship between liquid manipulation and micro-/nanostructured interfaces has gained much attention due to the wide potential applications in many fields, such as chemical and biomedical assays, environmental protection, industry, and even daily life. Much work has been done to construct various materials with interfacial liquid manipulation abilities, leading to a range of interesting applications. Herein, different fabrication methods from the top-down approach to the bottom-up approach and subsequent surface modifications of micro-/nanostructured interfaces are first introduced. Then, interactions between the surface and liquid, including liquid wetting, liquid transportation, and a number of corresponding models, together with the definition of hydrophilic/hydrophobic, oleophilic/olephobic, the definition and mechanism of superwetting, including superhydrophobicity, superhydrophilicity, and superoleophobicity, are presented. The micro-/nanostructured interface, with major applications in self-cleaning, antifogging, anti-icing, anticorrosion, drag-reduction, oil-water separation, water collection, droplet (micro)array, and surface-directed liquid transport, is summarized, and the mechanisms underlying each application are discussed. Finally, the remaining challenges and future perspectives in this area are included.
由于在化学和生物医学分析、环境保护、工业甚至日常生活等诸多领域的广泛应用潜力,人们对液体操纵与微/纳结构化界面之间的关系越来越关注。人们已经做了大量工作来构建具有界面液体操纵能力的各种材料,从而产生了一系列有趣的应用。本文首先介绍了从自上而下的方法到自下而上的方法的不同制造方法以及微/纳结构化界面的后续表面改性。然后,介绍了表面与液体之间的相互作用,包括液体润湿、液体输运以及一些相应的模型,以及亲水/疏水性、亲油/疏油性、超润湿的定义和机制,包括超疏水性、超亲水性和超疏油性。总结了微/纳结构化界面在自清洁、防雾、防冰、防腐、减阻、油水分离、水收集、液滴(微)阵列和表面导向液体传输等方面的主要应用,并讨论了每种应用的机理。最后,还包括了该领域的剩余挑战和未来展望。