College of Chemistry, Chemical Engineering and Materials Science, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Collaborative Innovation Centre of Functionalized Probes for Chemical Imaging in Universities of Shandong, Institute of Molecular and Nano Science, Shandong Normal University, Jinan, 250014, P. R. China.
Chem Commun (Camb). 2019 Sep 19;55(76):11426-11429. doi: 10.1039/c9cc05902d.
Highly regioselective Markovnikov hydrofunctionalization of alkenes was successfully realized via photoredox catalysis by introducing a urea group and fine tuning the hydrogen atom transfer catalysts. The anti-Markovnikov hydroamination of alkenes was also achieved with high yields and stereoselectivities in this work.
通过光氧化还原催化引入脲基并精细调整氢原子转移催化剂，成功实现了高区域选择性马氏加成反应。本工作还实现了反马氏加成反应，烯烃的加氢胺化反应具有高产率和立体选择性。
