利用荧光染料进行氧化还原开关催化。
Redox switchable catalysis utilizing a fluorescent dye.
机构信息
Department of Chemistry, Washington State University, Pullman, WA 99164, USA.
出版信息
Chem Commun (Camb). 2019 Sep 19;55(76):11430-11433. doi: 10.1039/c9cc05836b.
Abstract
This report describes the implementation of a 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye into the ligand framework of a Rh-based catalyst. The redox-active nature of the BODIPY dye is utilized to generate a catalyst that is capable of exhibiting redox-switchable catalytic behavior for the hydroboration of alkenes through a BODIPY-based reduction.
摘要
本报告介绍了将 4,4-二氟-4-硼-3a,4a-二氮杂-s-茚（BODIPY）染料引入铱基催化剂配体框架中的情况。BODIPY 染料的氧化还原活性被利用来生成一种催化剂，该催化剂能够通过基于 BODIPY 的还原表现出氧化还原开关催化行为，用于烯烃的硼氢化反应。
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