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1
Nanospace within metal-organic frameworks for gas storage and separation.金属有机框架内用于气体存储和分离的纳米空间。
Mater Today Nano. 2018 Jun;2. doi: 10.1016/j.mtnano.2018.09.003.
2
Microporous Metal-Organic Frameworks for Adsorptive Separation of C5-C6 Alkane Isomers.微孔金属有机骨架材料在 C5-C6 烷烃异构体吸附分离中的应用。
Acc Chem Res. 2019 Jul 16;52(7):1968-1978. doi: 10.1021/acs.accounts.8b00658. Epub 2019 Mar 18.
3
Harnessing Bottom-Up Self-Assembly To Position Five Distinct Components in an Ordered Porous Framework.利用自下而上的自组装将五种不同的组件定位在有序多孔框架中。
Angew Chem Int Ed Engl. 2019 Apr 8;58(16):5348-5353. doi: 10.1002/anie.201900863. Epub 2019 Mar 13.
4
Reversible Switching between Highly Porous and Nonporous Phases of an Interpenetrated Diamondoid Coordination Network That Exhibits Gate-Opening at Methane Storage Pressures.一种互穿类金刚石配位网络在甲烷储存压力下呈现门控开启现象，其在高孔隙率和无孔隙率相之间的可逆切换。
Angew Chem Int Ed Engl. 2018 May 14;57(20):5684-5689. doi: 10.1002/anie.201800820. Epub 2018 Apr 17.
5
A Metal-Organic Framework with Optimized Porosity and Functional Sites for High Gravimetric and Volumetric Methane Storage Working Capacities.一种具有优化的孔隙率和功能位点的金属有机骨架，用于实现高重量和体积甲烷存储工作容量。
Adv Mater. 2018 Apr;30(16):e1704792. doi: 10.1002/adma.201704792. Epub 2018 Mar 8.
6
A sol-gel monolithic metal-organic framework with enhanced methane uptake.一种具有增强甲烷吸附能力的溶胶-凝胶整体式金属有机框架。
Nat Mater. 2018 Feb;17(2):174-179. doi: 10.1038/nmat5050. Epub 2017 Dec 11.
7
Engineering of Pore Geometry for Ultrahigh Capacity Methane Storage in Mesoporous Metal-Organic Frameworks.介孔金属-有机骨架中超高压甲烷存储的孔结构工程。
J Am Chem Soc. 2017 Sep 27;139(38):13300-13303. doi: 10.1021/jacs.7b08347. Epub 2017 Sep 13.
8
Porous Metal-Organic Polyhedral Frameworks with Optimal Molecular Dynamics and Pore Geometry for Methane Storage.具有最佳分子动力学和孔几何形状的多孔金属-有机多面体框架用于甲烷存储。
J Am Chem Soc. 2017 Sep 27;139(38):13349-13360. doi: 10.1021/jacs.7b05453. Epub 2017 Sep 19.
9
Fine Tuning of MOF-505 Analogues To Reduce Low-Pressure Methane Uptake and Enhance Methane Working Capacity.调整 MOF-505 类似物以减少低压甲烷吸收并提高甲烷工作容量。
Angew Chem Int Ed Engl. 2017 Sep 11;56(38):11426-11430. doi: 10.1002/anie.201704974. Epub 2017 Aug 9.
10
Dynamic Spacer Installation for Multirole Metal-Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity.多用途金属有机骨架的动态间隔物安装：实现超高甲烷存储工作容量的多功能 MOFs 的新方向。
J Am Chem Soc. 2017 May 3;139(17):6034-6037. doi: 10.1021/jacs.7b01320. Epub 2017 Apr 19.

定制微孔金属有机骨架的孔几何形状和化学性质，以提高甲烷存储工作能力。

Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.

机构信息

State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China.

NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102, USA.

出版信息

Chem Commun (Camb). 2019 Sep 28;55(76):11402-11405. doi: 10.1039/c9cc06239d. Epub 2019 Sep 4.

DOI:10.1039/c9cc06239d
PMID:31482880
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7953312/
Abstract

We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm (STP) cm at 298 K and 5-80 bar.

摘要

我们意识到通过炔基或萘基取代一系列同构 MOF 中的苯基，可以调整孔径/几何形状和化学性质，从而优化甲烷存储工作容量，在 298 K 和 5-80 巴的条件下提供异常高的工作容量为 203 cm(STP)cm。