定制微孔金属有机骨架的孔几何形状和化学性质，以提高甲烷存储工作能力。
Tailoring the pore geometry and chemistry in microporous metal-organic frameworks for high methane storage working capacity.
机构信息
State Key Laboratory of Silicon Materials, Cyrus Tang Center for Sensor Materials and Applications, Department of Materials Science & Engineering, Zhejiang University, Hangzhou 310027, China.
NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-6102, USA.
出版信息
Chem Commun (Camb). 2019 Sep 28;55(76):11402-11405. doi: 10.1039/c9cc06239d. Epub 2019 Sep 4.
Abstract
We realized that tailoring the pore size/geometry and chemistry, by virtue of alkynyl or naphthalene replacing phenyl within a series of isomorphic MOFs, can optimize methane storage working capacities, affording an exceptionally high working capacity of 203 cm (STP) cm at 298 K and 5-80 bar.
摘要
我们意识到通过炔基或萘基取代一系列同构 MOF 中的苯基，可以调整孔径/几何形状和化学性质，从而优化甲烷存储工作容量，在 298 K 和 5-80 巴的条件下提供异常高的工作容量为 203 cm(STP)cm。
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