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丝瓜络衍生活性炭的卓越电容性能。

Superior Capacitive Performance of Active Carbons Derived from Loofah Sponge.

机构信息

Shandong Yateer Group Co., Ltd., Jinan, 250011, Shandong Province, People's Republic of China.

School of Mechanical Engineering, Shandong University of Technology, Zibo, 255049, Shandong Province, People's Republic of China.

出版信息

J Nanosci Nanotechnol. 2020 Apr 1;20(4):2416-2422. doi: 10.1166/jnn.2020.17180.

Abstract

In this paper, loofah sponge-based activated carbon (LAC) is prepared via loofah sponge as precursors and KOH as activator. N₂ adsorption, X-ray diffraction (XRD) and scanning electron microscope (SEM) were used to characterize the surface morphology and the structure of loofah sponge-based activated carbon. Cyclic voltammetry (CV), galvanostatic charge/discharge cycle and electrochemical impedance spectroscopy (EIS) were utilized to test electrochemical properties of loofah spongebased activated carbon. The results showed that loofah sponge-based activated carbon (LAC-700) prepared at 700 °C has the highest specific surface area (936 m²·g). The material delivers specific capacitance of 152.89 F·g at the current density of 0.1 A·g, and specific capacitance of 116.69 F·g at the current density of 5 A·g in 30 wt% KOH aqueous electrolyte.

摘要

本文以丝瓜络为前驱体,KOH 为活化剂,制备了丝瓜络基活性炭(LAC)。采用 N₂吸附、X 射线衍射(XRD)和扫描电子显微镜(SEM)对丝瓜络基活性炭的表面形貌和结构进行了表征。采用循环伏安(CV)、恒流充放电循环和电化学阻抗谱(EIS)测试了丝瓜络基活性炭的电化学性能。结果表明,在 700℃下制备的丝瓜络基活性炭(LAC-700)具有最高的比表面积(936 m²·g)。该材料在 30wt%KOH 水溶液电解质中,电流密度为 0.1 A·g 时的比电容为 152.89 F·g,电流密度为 5 A·g 时的比电容为 116.69 F·g。

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