Suleymanov Abdusalom A, Doll Martin, Ruggi Albert, Scopelliti Rosario, Fadaei-Tirani Farzaneh, Severin Kay
Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland.
Département de Chimie, Université de Fribourg, 1700, Fribourg, Switzerland.
Angew Chem Int Ed Engl. 2020 Jun 15;59(25):9957-9961. doi: 10.1002/anie.201908755. Epub 2019 Sep 26.
Tetraarylethenes are obtained by acid-induced coupling of vinyl triazenes with aromatic compounds. This new C-H activation route for the synthesis of aggregation-induced emission luminogens is simple, fast, and versatile. It allows the direct grafting of triarylethenyl groups onto a variety of aromatic compounds, including heterocycles, supramolecular hosts, biologically relevant molecules, and commercial polymers.
四芳基乙烯是通过乙烯基三氮烯与芳香族化合物的酸诱导偶联反应制得的。这种用于合成聚集诱导发光发光体的新型C-H活化途径简单、快速且通用。它能够将三芳基乙烯基直接接枝到各种芳香族化合物上，包括杂环化合物、超分子主体、生物相关分子和商业聚合物。
