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中国不同环境介质中多氯二苯并对二恶英和二苯并呋喃水平和形态的研究综述。

A review of levels and profiles of polychlorinated dibenzo-p-dioxins and dibenzofurans in different environmental media from China.

机构信息

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China; University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing, 100049, China.

State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China; University of Chinese Academy of Sciences, No. 19A Yuquan Road, Beijing, 100049, China.

出版信息

Chemosphere. 2020 Jan;239:124685. doi: 10.1016/j.chemosphere.2019.124685. Epub 2019 Sep 5.

Abstract

This review provides a summary of the levels and profiles of PCDD/Fs throughout China, as reported in peer reviewed literatures since 1997. The literature shows that PCDD/Fs are widespread in various environmental media including air, water, sediment, and soil. PCDD/Fs concentrations in air were relatively low in most regions, with only a few areas considered polluted. Many studies reported seasonal trends, with higher and lower concentrations in winter and summer, respectively. We analyzed the factors affecting the concentrations of dioxins in air and summarized the causes of seasonal changes. As hydrophobic organic compounds, PCDD/Fs readily accumulate in sediments. The distribution of dioxins in sediment in Bohai Sea area was mainly introduced and the factors affecting concentrations of dioxins were studied. The levels of dioxins in soil in different regions varied greatly, with higher levels in areas close to pollution sources. We examined the dioxins concentrations in soil in places where the levels were very low (including the Tibet Plateau and other remote areas), contaminated areas, and other areas. Apart from the contaminated areas, the dioxins concentrations in soil were low. The results of the relatively low number of studies that have investigated PCDD/Fs in water have reported no obvious pollution in some waters, apart from Dongting Lake. PCDD/Fs levels across China are similar to those worldwide. Point sources, mainly related to local geographic, economic, and historical factors, were the most common source of contamination. E-waste dismantling and chemical production has the greatest impact on PCDD/Fs in different media.

摘要

本综述总结了 1997 年以来中国各地区环境介质(包括空气、水、沉积物和土壤)中 PCDD/Fs 的浓度水平和分布特征。文献表明,PCDD/Fs 广泛存在于各种环境介质中。空气中 PCDD/Fs 的浓度在大多数地区相对较低,只有少数地区被认为受到污染。许多研究报告了季节性变化趋势,冬季和夏季的浓度分别较高和较低。我们分析了影响空气中二噁英浓度的因素,并总结了季节性变化的原因。由于 PCDD/Fs 是疏水性有机化合物,它们容易在沉积物中积累。本文主要介绍了渤海地区沉积物中二噁英的分布情况,并研究了影响其浓度的因素。不同地区土壤中二噁英的水平差异很大,靠近污染源的地区浓度较高。我们检测了污染程度较低的地区(包括青藏高原和其他偏远地区)、污染地区和其他地区土壤中二噁英的浓度。除了污染地区,土壤中二噁英的浓度较低。为数不多的关于水中 PCDD/Fs 的研究结果表明,除了洞庭湖,一些水域没有明显的污染。中国的 PCDD/Fs 水平与世界其他地区相似。点源污染主要与当地的地理、经济和历史因素有关,是最常见的污染来源。电子废物拆解和化学制品生产对不同介质中二噁英的影响最大。

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