Schuetz Roman, Maragh Janille M, Weaver James C, Rabin Ira, Masic Admir
D-REAMS Radiocarbon Laboratory, Weizmann Institute of Science, Rehovot, Israel.
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Sci Adv. 2019 Sep 6;5(9):eaaw7494. doi: 10.1126/sciadv.aaw7494. eCollection 2019 Sep.
The miraculously preserved 2000-year-old Dead Sea Scrolls, ancient texts of invaluable historical significance, were discovered in the mid-20th century in the caves of the Judean desert. The texts were mainly written on parchment and exhibit vast diversity in their states of preservation. One particular scroll, the 8-m-long Temple Scroll is especially notable because of its exceptional thinness and bright ivory color. The parchment has a layered structure, consisting of a collagenous base material and an atypical inorganic overlayer. We analyzed the chemistry of the inorganic layer using x-ray and Raman spectroscopies and discovered a variety of evaporitic sulfate salts. This points toward a unique ancient production technology in which the parchment was modified through the addition of the inorganic layer as a writing surface. Furthermore, understanding the properties of these minerals is particularly critical for the development of suitable conservation methods for the preservation of these invaluable historical documents.
保存异常完好的具有2000年历史的死海古卷是具有极高历史价值的古代文献,于20世纪中叶在犹地亚沙漠的洞穴中被发现。这些文献主要写在羊皮纸上,保存状态差异很大。其中一份特别的卷轴,长达8米的《圣殿卷轴》尤为引人注目,因其格外薄且呈明亮的象牙色。羊皮纸具有分层结构,由胶原质基础材料和一层非典型无机覆盖层组成。我们使用X射线和拉曼光谱分析了无机层的化学性质,发现了多种蒸发硫酸盐。这表明存在一种独特的古代制作工艺,即通过添加无机层作为书写表面来对羊皮纸进行改性。此外,了解这些矿物质的特性对于开发合适的保护方法以保存这些极其珍贵的历史文献尤为关键。