Formation of Two-Dimensional Network of Organic Charge-Transfer Complexes at the Air-Water Interface.

The air-water interface is an ideal platform to produce two-dimensional (2D) structures involving anything from simple organic molecules to supramolecular moieties by exploiting hydrophobic-hydrophilic interactions. Here, we show, using grazing incidence X-ray scattering, the formation of a 2D ordered structure of a charge-transfer (C-T) complex, namely, dodecyl methyl viologen (DMV) as acceptor and coronene tetracarboxylate potassium salt (CS) as donor, at the air-water interface. We have observed a phase transition in the 2D ordered structure as the area per molecule is decreased with increasing surface pressure in a Langmuir trough. The high-pressure ordering of the hydrocarbon chains associated with DMV destroys long-range C-T conjugation of DMV and CS at the air-water interface. Our results also explain the formation of DMV-CS cylindrical reverse micelles and eventually long nanowires that get formed in the self-assembly process in the bulk medium to preserve both the C-T conjugation and the organic tail-tail organization.