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基于新型二芳基乙烯的荧光开关用于铝的检测及逻辑电路构建。

Novel Diarylethene-Based Fluorescent Switching for the Detection of Al and Construction of Logic Circuit.

作者信息

Qiu Shouyu, Cui Shiqiang, Shi Fu, Pu Shouzhi

机构信息

Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China.

出版信息

ACS Omega. 2019 Aug 30;4(12):14841-14848. doi: 10.1021/acsomega.9b01432. eCollection 2019 Sep 17.

DOI:10.1021/acsomega.9b01432
PMID:31552323
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6751689/
Abstract

A novel photochromic diarylethene was synthesized successfully containing a phthalazine unit. Its multistate fluorescence switching properties were investigated by stimulating with UV/vis lights and Al/EDTA. The synthesized diarylethene displayed excellent selectivity to Al with a distinct fluorescence change, revealing that it could be used as a sensor for fluorescence identification of Al, and a logic circuit was constructed by utilizing this diarylethene molecular platform. Moreover, it also exhibited a high accuracy for the determination of Al in practical water samples.

摘要

成功合成了一种含有酞嗪单元的新型光致变色二芳基乙烯。通过紫外/可见光和铝/乙二胺四乙酸刺激研究了其多态荧光开关特性。合成的二芳基乙烯对铝表现出优异的选择性，荧光有明显变化，表明它可作为铝的荧光识别传感器，并利用该二芳基乙烯分子平台构建了一个逻辑电路。此外，它对实际水样中铝的测定也具有很高的准确性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/0430e07a4f85/ao9b01432_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/694d63e597f7/ao9b01432_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/e1a9cc5ccaf2/ao9b01432_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/b216a12c0143/ao9b01432_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/7e34d5d73488/ao9b01432_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/1a30cd62be6c/ao9b01432_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/aec957475d12/ao9b01432_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/e422e5a4eed6/ao9b01432_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/45e083ffc7bf/ao9b01432_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/c62318cfcf21/ao9b01432_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/0430e07a4f85/ao9b01432_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/694d63e597f7/ao9b01432_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/e1a9cc5ccaf2/ao9b01432_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/b216a12c0143/ao9b01432_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/7e34d5d73488/ao9b01432_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/1a30cd62be6c/ao9b01432_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/aec957475d12/ao9b01432_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/e422e5a4eed6/ao9b01432_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/45e083ffc7bf/ao9b01432_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/c62318cfcf21/ao9b01432_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/752f/6751689/0430e07a4f85/ao9b01432_0010.jpg

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