基于钌配合物的高效且稳定的分子水氧化催化剂。
Highly efficient and robust molecular water oxidation catalysts based on ruthenium complexes.
作者信息
Wang Lei, Duan Lele, Wang Ying, Ahlquist Mårten S G, Sun Licheng
机构信息
Department of Chemistry, School of Chemical Science and Engineering, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden.
出版信息
Chem Commun (Camb). 2014 Nov 4;50(85):12947-50. doi: 10.1039/c4cc05069j.
PMID:25219682
Abstract
Two monomeric ruthenium molecular catalysts for water oxidation have been prepared, and both of them show high activities in pH 1.0 aqueous solutions, with an initial rate of over 1000 turnover s(-1) by complex 1, and a turnover number of more than 100,000 by complex 2.
摘要
已经制备了两种用于水氧化的单体钌分子催化剂，它们在pH 1.0的水溶液中均表现出高活性，配合物1的初始速率超过1000次周转秒⁻¹，配合物2的周转数超过100,000。
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