Hou Huilin, Zeng Xiangkang, Zhang Xiwang
Department of Chemical Engineering, Monash University, Clayton, VIC, 3800, Australia.
Institute of Materials, Ningbo University of Technology, Ningbo, 315016, P. R. China.
Angew Chem Int Ed Engl. 2020 Sep 28;59(40):17356-17376. doi: 10.1002/anie.201911609. Epub 2020 May 18.
Hydrogen peroxide (H O ) has received increasing attention because it is not only a mild and environmentally friendly oxidant for organic synthesis and environmental remediation but also a promising new liquid fuel. The production of H O by photocatalysis is a sustainable process, since it uses water and oxygen as the source materials and solar light as the energy. Encouraging processes have been developed in the last decade for the photocatalytic production of H O . In this Review we summarize research progress in the development of processes for the photocatalytic production of H O . After a brief introduction emphasizing the superiorities of the photocatalytic generation of H O , the basic principles of establishing an efficient photocatalytic system for generating H O are discussed, highlighting the advanced photocatalysts used. This Review is concluded by a brief summary and outlook for future advances in this emerging research field.
过氧化氢(H₂O₂)受到了越来越多的关注,因为它不仅是一种用于有机合成和环境修复的温和且环保的氧化剂,还是一种有前景的新型液体燃料。通过光催化生产H₂O₂是一个可持续的过程,因为它以水和氧气作为原料,以太阳光作为能源。在过去十年中,已经开发出了令人鼓舞的光催化生产H₂O₂的工艺。在本综述中,我们总结了光催化生产H₂O₂工艺开发方面的研究进展。在简要介绍强调光催化生成H₂O₂的优势之后,讨论了建立高效光催化体系以生成H₂O₂的基本原理,重点介绍了所使用的先进光催化剂。本综述最后对这一新兴研究领域未来的进展进行了简要总结和展望。