Design of Multifunctional Fluorescent Hybrid Materials Based on SiO Materials and Core-Shell Fe O @SiO Nanoparticles for Metal Ion Sensing.

Hybrid fluorescent materials constructed from organic chelating fluorescent probes and inorganic solid supports by covalent interactions are a special type of hybrid sensing platform that has gained much interest in the context of metal ion sensing applications owing to their excellent advantages, recyclability, and solubility/dispersibility in particular, as compared with single organic fluorescent molecules. In recent decades, SiO materials and core-shell Fe O @SiO nanoparticles have become important inorganic solid materials and have been used as inorganic solid supports to hybridize with organic fluorescent receptors, resulting in multifunctional fluorescent hybrid systems for potential applications in sensing and related research fields. Therefore, recent progress in various fluorescent-group-functionalized SiO materials is reviewed, with a focus on mesoporous silica nanoparticles and core-shell Fe O @SiO nanoparticles, as interesting fluorescent organic-inorganic hybrid materials for sensing applications toward essential and toxic metal ions. Selective examples of other types of silica/silicon materials, such as periodic mesoporous organosilicas, solid SiO nanoparticles, fibrous silica spheres, silica nanowires, silica nanotubes, and silica hollow microspheres, are also mentioned. Finally, relevant perspectives of metal-ion-sensing-oriented silica-fluorescent probe hybrid materials are provided.