Marreiros João, Van Dommelen Lenz, Fleury Guillaume, de Oliveira-Silva Rodrigo, Stassin Timothée, Iacomi Paul, Furukawa Shuhei, Sakellariou Dimitrios, Llewellyn Philip L, Roeffaers Maarten, Ameloot Rob
Centre for Membrane Separations, Adsorption, Catalysis and Spectroscopy for Sustainable Solutions (cMACS), KU Leuven, Celestijnenlaan 200F p.o. box 2454, 3001, Leuven, Belgium.
Aix-Marseille University, CNRS, MADIREL (UMR 7246), 13013, Marseille, France.
Angew Chem Int Ed Engl. 2019 Dec 16;58(51):18471-18475. doi: 10.1002/anie.201912088. Epub 2019 Nov 4.
Zeolitic imidazolate frameworks (ZIFs) are a sub-class of metal-organic frameworks (MOFs). Although generally stable, ZIFs can undergo post-synthetic linker exchange (PSLE) in solution under mild conditions. Herein, we present a novel, solvent-free approach to post-synthetic linker exchange through exposure to linker vapor.
沸石咪唑酯骨架材料（ZIFs）是金属有机骨架材料（MOFs）的一个子类。尽管ZIFs通常很稳定，但在温和条件下，它们在溶液中可发生后合成连接体交换（PSLE）。在此，我们提出一种通过暴露于连接体蒸汽进行后合成连接体交换的新型无溶剂方法。
