Institute of Engineering Thermophysics,Chinese Academy of Sciences, Beijing 100190, China.
Yangtze River Delta Research Institute of NPU, Northwestern Polytechnical University, Taicang, Jiangsu 215400, China.
Phys Rev E. 2019 Sep;100(3-1):032101. doi: 10.1103/PhysRevE.100.032101.
Rayleigh and Onsager showed that in the regime where the flows are small and the thermodynamic forces vary slowly, the entropy generation rate is linearly related to the flows, and the flows are related to the gradient of the forces. Hence, the Rayleigh-Onsager dissipation is only applicable to linear irreversible thermodynamics. We introduce the extension of Rayleigh-Onsager dissipation to highly nonlinear dissipation to treat nonlinear irreversible thermodynamics. This extension fulfills the positive entropy generation criterion. To demonstrate this nonlinear dissipation, we apply it to obtain the generalized hydrodynamics from the kinetic theory according to Eu theory. Specifically, it provides an alternative evolution for a stress tensor and heat flux. The challenging problems of nonlinear irreversible thermodynamics, as represented by nonequilibrium flows, are investigated. The result implies that this study provides a promising alternative to obtain a unified framework for modeling both equilibrium and nonequilibrium gas flows.
瑞利和昂萨格表明,在流动较小且热力学力变化缓慢的情况下,熵产生率与流动呈线性关系,而流动与力的梯度有关。因此,瑞利-昂萨格耗散仅适用于线性不可逆热力学。我们将瑞利-昂萨格耗散扩展到高度非线性耗散,以处理非线性不可逆热力学。这种扩展满足正熵产生准则。为了展示这种非线性耗散,我们根据欧几里得理论从运动理论中应用它来获得广义流体动力学。具体来说,它为应力张量和热通量提供了另一种演化。我们研究了以非平衡流为代表的非线性不可逆热力学的挑战性问题。结果表明,本研究为获得统一的模型框架提供了一种有前途的方法,用于模拟平衡和非平衡气体流动。