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基于六方相 SnS 纳米片的室温高灵敏度 NO 气体传感器。

Highly sensitive NO gas sensors based on hexagonal SnS nanoplates operating at room temperature.

机构信息

Key Laboratory of Thin Film and Microfabrication (Ministry of Education), Department of Micro/Nano Electronics, School of Electronic Information and Electrical Engineering, Center of Hydrogen Science, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China.

出版信息

Nanotechnology. 2020 Feb 7;31(7):075501. doi: 10.1088/1361-6528/ab5271. Epub 2019 Oct 29.

Abstract

While continuously developing high-performance chemoresistive gas sensors, reducing device power consumption is not negligible. One of the most efficient ways is to enable gas sensors to work close to room temperature. In this work, we present a gas sensor based on hexagonal tin disulfide (SnS) nanoplates for sensitive and reversible NO sensing at room temperature. Two-dimensional SnS nanoplates are synthesized via a facile hydrothermal method using Triton X-100 as a surfactant. The sensor exhibits a high response of 15.6 for 50 ppm NO with an experimental limit of detection of 50 ppb at room temperature. Besides, excellent linearity, outstanding selectivity, and reliable long-term stability within 40 d are also demonstrated during the experiment process. The sensing mechanism of this sensor could be explained as the physisorption and charge transfer between NO molecules and SnS nanoplates, which make it possible for the sensor to work at such a low operating temperature. Our research resulted in a SnS nanoplate-based sensor that may pave a new way for effective NO detection in the future.

摘要

在不断开发高性能化学电阻式气体传感器的同时,降低器件的功耗也不容忽视。其中最有效的方法之一是使气体传感器能够在接近室温的条件下工作。在这项工作中,我们提出了一种基于六方相二硫化锡(SnS)纳米片的气体传感器,用于在室温下对 NO 进行灵敏和可逆的检测。二维 SnS 纳米片是通过使用 Triton X-100 作为表面活性剂的简单水热法合成的。该传感器对 50 ppm 的 NO 表现出 15.6 的高响应,实验检测限为 50 ppb,在室温下。此外,在实验过程中还表现出了出色的线性度、优异的选择性和可靠的长期稳定性,可维持 40 天。该传感器的传感机制可以解释为 NO 分子与 SnS 纳米片之间的物理吸附和电荷转移,这使得传感器能够在如此低的工作温度下工作。我们的研究得到了一种基于 SnS 纳米片的传感器,这可能为未来有效的 NO 检测开辟新途径。

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