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阿尔弗雷德·沃纳:被忽视的元素周期表天才

Alfred Werner: Overlooked Genius of the Periodic System.

机构信息

Chemistry Education Research and Practice Laboratory, SCAMT Institute, ITMO University, 9 Lomonosova Str., Saint Petersburg, 191002, Russian Federation.

出版信息

Chemistry. 2019 Dec 10;25(69):15707-15709. doi: 10.1002/chem.201904321. Epub 2019 Nov 4.

Abstract

2019, which was proclaimed by the United Nations as the International Year of the Periodic Table, sees one hundred years since Alfred Werner, the first Swiss to receive a Nobel Prize in chemistry, passed away. The undoubted father of coordination chemistry, he is also well-known for influencing many other fields of chemistry, including organic, inorganic, organometallic, bioinorganic, and stereochemistry. However, one of his more rare and unique contributions to chemistry, his 1905 version of the periodic system, to this day remains overlooked. The simple and elegant idea which he used to construct his periodic table has not been communicated to the English-speaking world, because Alfred Werner published his only original paper on the periodic table in German. Werner's simple mathematical approach lead to overwhelming success with anticipating the future f-block. He managed to predict almost perfectly the number of lanthanides, which was hotly debated at that time. Werner's genius vision was considerably ahead of its time. It was not until the 1940s and the discovery of actinide series when the idea of representing the elements as a 32-column periodic table finally became justified.

摘要

2019 年被联合国宣布为国际化学元素周期表年,距离第一位获得诺贝尔化学奖的瑞士人阿尔弗雷德·沃纳(Alfred Werner)逝世已经过去了一百年。作为配位化学的当之无愧的奠基人,他也因影响包括有机、无机、有机金属、生物无机和立体化学在内的许多其他化学领域而闻名。然而,他对化学的一个更罕见和独特的贡献,即他在 1905 年提出的元素周期表,至今仍被忽视。他用来构建元素周期表的简单而优雅的思想并没有传达给英语世界,因为阿尔弗雷德·沃纳(Alfred Werner)仅用德语发表了他关于元素周期表的唯一原创论文。沃纳(Werner)的简单数学方法在预测未来的 f 区方面取得了压倒性的成功。他成功地预测了当时备受争议的镧系元素的数量,几乎完美无缺。沃纳(Werner)的天才眼光大大超越了时代。直到 20 世纪 40 年代发现锕系元素系列,将元素表示为 32 列的元素周期表的想法最终才得到证实。

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