College of Chemistry and Chemical Engineering, Henan Key Laboratory of Function-Oriented Porous Materials , Luoyang Normal University , Luoyang 471934 , P. R. China.
College of Chemistry and Chemical Engineering , Henan Polytechnic University , Jiaozuo 454000 , P. R. China.
Inorg Chem. 2019 Nov 18;58(22):15013-15016. doi: 10.1021/acs.inorgchem.9b02203. Epub 2019 Nov 6.
Highly dense packing of chromophoric linkers is achieved in a novel pyrene-based metal-organic framework (MOF), [Zn(TBAPy)(HO)], induced by an ionic liquid. This MOF displays a quick response to visible-light irradiation (photocurrent density of up to 4.492 μA cm) and is capable of repetitive on-off photocurrent switching with a large on-off ratio (37.55).
在一种新型基于苝的金属-有机骨架（MOF）[Zn(TBAPy)(HO)]中，通过离子液体实现了发色链接物的高密度堆积。该 MOF 对可见光照射具有快速响应（光电流密度高达 4.492 μA cm），并且能够进行具有大开关比（37.55）的重复通断光电流切换。
